(Trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu)

Philipp Schmid; Karin Bartl; Robert Saf; Takahiro Sasamori; Vladimir Ya Lee; Frank Uhlig

doi:10.1021/acs.organomet.5c00088

(Trialkylsilyl)germanes (^tBuMeRSi)GeH₃ (R = Me, ^tBu)

Philipp Schmid, Karin Bartl, Robert Saf, Takahiro Sasamori, Vladimir Ya Lee^*, Frank Uhlig^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Stable (trialkylsilyl)germanes (^tBuMeRSi)GeH₃ (R = Me, ^tBu) were prepared, using a novel synthetic approach, and characterized. This approach includes the initial preparation of the (trialkylsilyl)(p-tolyl)germanes (^tBuMeRSi)Ge(p-tolyl)H₂, chlorodearylation of which produced (trialkylsilyl)chlorogermanes (^tBuMeRSi)GeClH₂, which were finally reacted with LiAlH₄ to produce the desired (trialkylsilyl)germanes (^tBuMeRSi)GeH₃. These compounds have the potential to be precursors for the production of germanium nanoparticles and oligomers, as the prospective materials of the new generation.

Original language	English
Pages (from-to)	1000-1005
Number of pages	6
Journal	Organometallics
Volume	44
Issue number	9
Early online date	30 Apr 2025
DOIs	https://doi.org/10.1021/acs.organomet.5c00088
Publication status	Published - 12 May 2025

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.organomet.5c00088

Cite this

@article{307f3681bc9343ff8e6be1b1b1dfc81b,

title = "(Trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu)",

abstract = "Stable (trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu) were prepared, using a novel synthetic approach, and characterized. This approach includes the initial preparation of the (trialkylsilyl)(p-tolyl)germanes (tBuMeRSi)Ge(p-tolyl)H2, chlorodearylation of which produced (trialkylsilyl)chlorogermanes (tBuMeRSi)GeClH2, which were finally reacted with LiAlH4 to produce the desired (trialkylsilyl)germanes (tBuMeRSi)GeH3. These compounds have the potential to be precursors for the production of germanium nanoparticles and oligomers, as the prospective materials of the new generation.",

author = "Philipp Schmid and Karin Bartl and Robert Saf and Takahiro Sasamori and Lee, {Vladimir Ya} and Frank Uhlig",

note = "Publisher Copyright: {\textcopyright} 2025 American Chemical Society.",

year = "2025",

month = may,

day = "12",

doi = "10.1021/acs.organomet.5c00088",

language = "English",

volume = "44",

pages = "1000--1005",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - (Trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu)

AU - Schmid, Philipp

AU - Bartl, Karin

AU - Saf, Robert

AU - Sasamori, Takahiro

AU - Lee, Vladimir Ya

AU - Uhlig, Frank

PY - 2025/5/12

Y1 - 2025/5/12

N2 - Stable (trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu) were prepared, using a novel synthetic approach, and characterized. This approach includes the initial preparation of the (trialkylsilyl)(p-tolyl)germanes (tBuMeRSi)Ge(p-tolyl)H2, chlorodearylation of which produced (trialkylsilyl)chlorogermanes (tBuMeRSi)GeClH2, which were finally reacted with LiAlH4 to produce the desired (trialkylsilyl)germanes (tBuMeRSi)GeH3. These compounds have the potential to be precursors for the production of germanium nanoparticles and oligomers, as the prospective materials of the new generation.

AB - Stable (trialkylsilyl)germanes (tBuMeRSi)GeH3 (R = Me, tBu) were prepared, using a novel synthetic approach, and characterized. This approach includes the initial preparation of the (trialkylsilyl)(p-tolyl)germanes (tBuMeRSi)Ge(p-tolyl)H2, chlorodearylation of which produced (trialkylsilyl)chlorogermanes (tBuMeRSi)GeClH2, which were finally reacted with LiAlH4 to produce the desired (trialkylsilyl)germanes (tBuMeRSi)GeH3. These compounds have the potential to be precursors for the production of germanium nanoparticles and oligomers, as the prospective materials of the new generation.

UR - http://www.scopus.com/inward/record.url?scp=105003917821&partnerID=8YFLogxK

U2 - 10.1021/acs.organomet.5c00088

DO - 10.1021/acs.organomet.5c00088

M3 - Article

AN - SCOPUS:105003917821

SN - 0276-7333

VL - 44

SP - 1000

EP - 1005

JO - Organometallics

JF - Organometallics

IS - 9

ER -

(Trialkylsilyl)germanes (^tBuMeRSi)GeH₃ (R = Me, ^tBu)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this