NIR-emitting aza-BODIPY dyes – new building blocks for broad-range optical pH sensors

M. Strobl; T. Rappitsch; S.M. Borisov; T. Mayr; I. Klimant

doi:10.1039/C5AN01389E

NIR-emitting aza-BODIPY dyes – new building blocks for broad-range optical pH sensors

M. Strobl, T. Rappitsch, S.M. Borisov, T. Mayr, I. Klimant

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Abstract

New aza-BODIPY indicators which cover the pH scale from 1.5 to 13 are presented. The new indicators feature absorption/emission bands in the red/near-infrared (NIR) spectral region, exhibit high molar absorption coefficients (∼ 80 000 M−1 cm−1) and show good quantum yields (∼20%). All dyes represent promising building blocks for the development of a broad-range sensor for various pH ranges. Combination of four of these pH indicators yields a pH sensor with an extended dynamic range from pH 2 to 9.

Original language	English
Pages (from-to)	7150-7153
Journal	Analyst
Volume	140
DOIs	https://doi.org/10.1039/C5AN01389E https://doi.org/10.1039/c5an01389e
Publication status	Published - 2015

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Advanced Materials Science

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Basic - Fundamental (Grundlagenforschung)

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10.1039/C5AN01389ELicence: CC BY 4.0
10.1039/c5an01389e

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title = "NIR-emitting aza-BODIPY dyes – new building blocks for broad-range optical pH sensors",

abstract = "New aza-BODIPY indicators which cover the pH scale from 1.5 to 13 are presented. The new indicators feature absorption/emission bands in the red/near-infrared (NIR) spectral region, exhibit high molar absorption coefficients (∼ 80 000 M−1 cm−1) and show good quantum yields (∼20\%). All dyes represent promising building blocks for the development of a broad-range sensor for various pH ranges. Combination of four of these pH indicators yields a pH sensor with an extended dynamic range from pH 2 to 9.",

author = "M. Strobl and T. Rappitsch and S.M. Borisov and T. Mayr and I. Klimant",

year = "2015",

doi = "10.1039/C5AN01389E",

language = "English",

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journal = "Analyst",

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AU - Rappitsch, T.

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AU - Mayr, T.

AU - Klimant, I.

PY - 2015

Y1 - 2015

N2 - New aza-BODIPY indicators which cover the pH scale from 1.5 to 13 are presented. The new indicators feature absorption/emission bands in the red/near-infrared (NIR) spectral region, exhibit high molar absorption coefficients (∼ 80 000 M−1 cm−1) and show good quantum yields (∼20%). All dyes represent promising building blocks for the development of a broad-range sensor for various pH ranges. Combination of four of these pH indicators yields a pH sensor with an extended dynamic range from pH 2 to 9.

AB - New aza-BODIPY indicators which cover the pH scale from 1.5 to 13 are presented. The new indicators feature absorption/emission bands in the red/near-infrared (NIR) spectral region, exhibit high molar absorption coefficients (∼ 80 000 M−1 cm−1) and show good quantum yields (∼20%). All dyes represent promising building blocks for the development of a broad-range sensor for various pH ranges. Combination of four of these pH indicators yields a pH sensor with an extended dynamic range from pH 2 to 9.

UR - https://www.scopus.com/pages/publications/84944145331

U2 - 10.1039/C5AN01389E

DO - 10.1039/C5AN01389E

M3 - Article

SN - 0003-2654

VL - 140

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JO - Analyst

JF - Analyst

ER -

NIR-emitting aza-BODIPY dyes – new building blocks for broad-range optical pH sensors

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